September 23, 2011
PLEASE NOTE: The formula I have posted for converting %Crude Protein into % Nitrogen has been called into question. I have checked my resources and CONFIRM that in order to convert the %Crude Protein Number into %Nitrogen, DIVIDE the Crude Protein Number by 6.25%. If you wish to convert a %Nitrogen value to Crude Protein, MULTIPLY the % Nitrogen by 6.25% . Here is a quotation from Rose Scientific Ltd. regarding the Kjeldahl method of determining nitrogen content:
"Calculation
"After all this chemistry it is now time to calculate the amount of nitrogen present in the sample. This calcualtion can either be performed as percent nitrogen or percent protein. For percent nitrogen:
% N - 14.01 x (ml titrant - ml blank) - (N of titrant ) x 100
Sample Wt. (grams) x 1000
It has been shown that protein is 16% nitrogen. (Wheat and dairy products are some exceptions.) By dividing 100 by 16, we get the conversion factor for nitrogen to protein of 6.25. Hence, the percent protein is calculated as follows:
% Protein = 6.25 x % N"
It follows then, that in order to find the %N in the Crude Protein analysis, that
% N = CP DIVIDED by 6.25
Just as stated below.
IF YOU FEEL THIS IS INCORRECT, or anything else on this blog, PLEASE SAY SO and give me the opportunity to either correct or justify any statement I have made. This blog is for the benefit of everyone. It needs to be accurate! Thank you!
_____________________________________________
I guess in this year of deep droughts in certain parts of the country, I should be grateful for any hay at all. But what I got this year, and the amount I paid for it, is a crushing blow for someone who has worked so hard to get horse hay “right.”
Our horses are both “insulin resistant.” For the non-horse owner, that means they have a sort of type II diabetes which has been brought about by excessive sugars in their diet. These sugars are largely to be blamed on deranged soil mineral balances, either by the natural absence of minerals in the soil, or by excessive applications of certain minerals by the grower.
As Wm. Albrecht said, the pedigree of the plant is worthless if it is grown in unbalanced soil. So we have made no effort to plant supposedly low sugar grasses. Our hay ground is populated with naturalized species.
We have worked for several years to balance our soil mineral content to produce hay that is nutritionally balanced for our horses. Millions of years of excessive rainfall have leached much of the mineral fertility out of the soil. This has produced forage that was deadly deficient in almost every category. Our efforts to return mineral fertility to our soil have been expensive, and more successful than I realized. But for various, valid reasons, I tossed it out the window this year and purchased hay from another source.
One of the results of our fertility program has been an explosion of legumes, notably vetch. This would be a fine thing for grazing ruminants, but for making horse hay, it was definitely not what we had in mind. Clovers for instance, can give horses “the slobbers.” Too many legumes can bring the protein levels up to excessive amounts for mature horses, which only require about 8-9% protein.
For the last two years, the vetch has run rampant. Vetch is a spindly, viney legume that clamors up the grasses toward the light. In 2010, it was so heavy that it gummed up the haying equipment. Our hay guys were very impressed, thinking that was about some of the finest local hay (standing) they’d seen!
In 2009, the hay got cut in June, as I recall, before the vetch really got crazy, and before it had all gone to seed and shattered. That year we produced quite a fine, low carbohydrate hay that was very fit for our at-risk horses. Some of the mineral were in short supply, but it would be hard to get everything exactly perfect.
In 2010, our roughly 6 acres of hay ground produced 20 tons of hay, despite being grazed almost right up to haying by sheep. At that time, we had numerous livestock animals besides the two horses, and we needed those 20 tons. This was stuff that was loaded with vetch. Overall, the numbers were within reason for insulin resistant horses, although the nonstructural carbohydrate number had crept up to about 11%. We want to keep it below 10%. The biggest problem we had was that the baled hay was over 20% moisture, where it should probably have had no more than 10%, so much of it got musty/moldy. This was not the fault of the hay balers or anything really, except perhaps that the ground was still moist from a terribly wet spring. The weather was just not conducive to drying broad-leaved legumes. It hardly ever is in this part of the country. As it was, the hay was baled in mid-July, when the vetch had shattered and was mostly dead. Certainly past its prime.
Another strike against growing legumes for insulin resistant horse hay. Our hay ground is also now positively loaded with clover and black medic, a relative of alfalfa.
We were our own greatest liability. I was 59 in 2010 and Bob was 70. Despite having purchased and refurbished an old Henry bale loader, the work of picking up 20 tons of hay and putting it in the hay loft nearly killed us. It took us a week to bring it in out of the field, and about two weeks to recover!
At that time, we had numerous livestock animals besides the two horses, and we needed those 20 tons.
At some point during the fall/winter, we decided that our sheep operation was not gratifying enough to continue the backbreaking work, so we eliminated all the ruminants. Two horses remained…two horses on strict diets. We no longer needed all that hay, and so stupidly, we sold half of it. We anticipated having to put up another crop in 2011, and we needed the storage space.
The 2011 winter and spring rains drove on relentlessly, and it was obvious we were in for another late haying. It nearly killed us physically to put up the last crop, and we dreaded the work ahead of us. But worst of all, three rains in June permanently lodged much of the crop. The vetch growing up the grass mashed it over and it never stood again. Much of it began to ferment/rot underneath.
That was the death knell for the 2011 crop. It was something we could do nothing about, so the decision was made not to harvest. Even after we had spent about $1800 on soil minerals the previous fall.
It was rumored that the local hay broker was now selling “low carb” hay. We paid a visit to the broker and found that he had about 7 tons of 2010 low carb hay left over and no real prospects for finding any more. So I put my name on the year old “low carb” hay and paid $255 per ton, plus delivery. This hay is monoculture orchard grass hay, commercially grown in Central Oregon. The soil there is basically volcanic ash/sand, irrigated desert.
Now, you must know that desperate horse owners have been paying top dollar for rained-on central Oregon orchard grass hay, because supposedly the rain washes out the sugar.
This was what I had just bought: Year old, rained on central Oregon orchard grass hay, for $255 per ton.
While the hay was still on the truck, I took my sample and sent it in to Holmes Lab for analysis. The results are an absolutely crushing blow, but have once again given tongue to my passion for soil mineralization.
What I am about to share with you is a comparison of the purchased hay versus the home grown hay, and any supporting documentation that I can find to help you understand the profoundness of the differences.
Please note, that because of our constant leaching due to heavy rainfall, and considerable crop uptake, we make heavy applications of certain minerals each year, according to consultant recommendations. The cost of the homegrown hay is very near the cost of the purchased hay. In our circumstance, concern for animal health must play into our decision to shoulder the work and expense of growing hay ourselves versus buying it and letting others do the work.
Another consideration at this point, is the convenience of Oregon’s shipping ports to the Orient. Asia is buying Oregon hay at record levels which are only likely to increase. Trying to grow our own is hopefully a hedge against rising prices and scarcity.
The Comparison
References to horse nutritional requirements are extracted from: Nutritional Management for Horses, AS-429, Purdue University Cooperative Extension Service http://www.ces.purdue.edu/extmedia/AS/AS-429.html
CRUDE PROTEIN
Nutritional Requirement (mature horses): 8-10%
Purchased hay: 10.30%
Homegrown hay: 11.19%
Discussion: The first thing that you need to understand without question is that “crude protein” only refers to the amount of nitrogen in the hay. The CP number absolutely does NOT reflect the amount of “true” protein contained in the hay. Thus the CP may actually reflect an excessive amount of nitrogen that was used to produce a bumper crop as opposed to true nutrition. How do we know? And what are the consequences of excessive non-protein nitrogen?
Most proteins contain about 16% nitrogen, so a mathematical equation was devised to estimate true protein in our hay. In order to estimate how much nitrogen is in your Crude Protein value, divide the CP by 6.25%.
According to Jerry Brunetti, holistic livestock nutritionist, the only real tool we have to evaluate the CP value on a hay analysis is the sulphur value on the analysis. Sulphur is required to help turn some of that nitrogen into protein. Here is his formula: A healthy ratio of nitrogen to sulphur is 10:1, that is, 10 parts nitrogen to one part sulphur. To get a feel for how much “true” versus “funny” (nitrogen) protein is REALLY in your hay, divide the nitrogen by the sulphur value to determine your N:S ratio.
(BE SURE to order sulphur analysis when you send in your hay sample to the lab. Many labs don’t offer it automatically)
To determine how much sulphur the hay needs to achieve a 10:1 N:S ratio, first determine your nitrogen content. For the commercial hay, we have 10.30% CP. 10:30 CP ÷ 6.25 = 1.648 x .10 = .1648. The amount of sulphur required in this hay to help insure true protein versus excess non-protein nitrogen is .1648. The hay contains .15% sulphur.
The horse’s requirement for sulphur is .15% with a maximum tolerable level of 1.25%. Keep in mind that NRC requirements are generally expressed as the lowest amount required to prevent clinical disease. This hay is not adequate in sulphur to produce such essential amino acids as sulphur-bearing methionine.
The homegrown hay is produced on sulphur-enriched soil. However, sulphur is susceptible to leaching, so even though we apply it, some leaching occurs during winter rains.
The CP of the homegrown hay is 11.19%. 11.19÷6.25 = 1.79% x .10 = .179% sulphur required to balance the nitrogen. The homegrown hay contains .19%. There is adequate sulphur available to help convert the nitrogen into essential amino acids, along with meeting the horses’ nutritional requirement for sulphur.
Reference: Jerry Brunetti, True Protein vs. ‘Funny Protein’ www.acresuse.com/toolbox/reprints/Brunetti_Protein.pdf
NON-STRUCTURAL/WATER SOLUBLE CARBOHYDRATES (SUGAR AND STARCH)
For insulin-resistant horses, I would like to see the NSC below 12%. 10% or lower would be better.
Purchased Hay: 5.82%
Homegrown Hay: 10.89%
I put the homegrown hay in red because even though it is just barely within boundaries, the rained on hay beats the homegrown hay hands down for low sugar and starch. Breaking the numbers down further:
Sugar, Purchased Hay: 5.18%
Sugar, Homegrown Hay: 7.53%
Starch, Purchased Hay: .64%
Starch, Homegrown Hay: 3.36%
Huge difference in the starch content. It’s too bad we don’t have a pre-rain and post-rain evaluation on the purchased hay. And I wish there was a way to determine what other vitamins and other soluble nutrients were washed out of the hay along with the sugar. I know it didn’t make a bit of difference to the potassium content in the rained on hay, as it is excessively high. This I believe brands the rained on hay even more dangerous than the homegrown hay as you continue to read through the comparison until you get to the grass tetany ratio.
CALCIUM
Nutritional Requirement: .25 -.30%
Purchased Hay: .20
Homegrown Hay: .50
Many of us believe that the nutritional requirements assigned by the National Research Council are the bare minimums to prevent clinical disease. As long as everything is in balance, perhaps 150% of the NRC requirements would be more healthful.
Right off the bat, we see that the commercially grown hay is deficient in calcium. But it gets worse…much worse, as you will see.
The homegrown hay is certainly adequate at 200% of the basic need. Yet again, there are factors involved that may prevent the metabolism of the calcium. I will share an anecdote later.
PHOSPHORUS
Nutritional Requirement: .20-.25%
Purchased Hay: .29
Homegrown Hay: .18
Here the mineralization program on our hay field is not yet up to full speed, despite annual applications of phosphorus. It is a work in progress.
Phosphorus must be available in a specific ratio with calcium. That ratio is between 1:1 and 3:1. With a deficiency of calcium or an imbalance of the two elements, the horse’s bones will become soft and weak or simply won’t develop properly.
Ca:P RATIO
Nutritional requirement: 1:1 – 3:1 Calcium to Phosphorus
Purchased Hay: 0.69:1
Homegrown Hay: 2.8:1
Despite the deficiency of phosphorus in the homegrown hay, the Ca:P ratio is still within bounds. The commercial hay loses pretty badly.
MAGNESIUM
Nutritional Requirement: .1 - .15
Purchased Hay: .13
Homegrown Hay: .18
Magnesium is known to be one of the key minerals for metabolic health. In our neck of the woods, magnesium (Mg) is rarely recommended as a fertility element because it does not increase yield. Livestock owners with cattle and sheep are expected to deal with grass tetany problems by setting out magnesium blocks at times of the year when magnesium is known to be in short supply in the grass. From what I have gathered over the years, I believe strongly that deficient magnesium may be strongly suspect in metabolic diseases such as inexplicable winter laminitis attacks. I will elaborate when I get down to potassium.
Although the homegrown hay is adequate for Mg, it could be better. It is not for failing to add magnesium to the soil. It is more a matter of difficulty moving it into the grass plants in cold spring soil, when microbial activity is low. It may be necessary to provide a stimulant to the microbes in the spring, to improve the magnesium value.
As with Calcium and Phosphorus, so is there a correct ratio between Calcium and Magnesium. That ratio is 2:1.
Ca:Mg RATIO
Nutritional Requirement: 2:1 Calcium to Magnesium
Purchased Hay: 1.5:1
Homegrown Hay: 2.7:1
So even though the individual numbers in the homegrown hay are better than in the purchased hay, we could stand to add more Mg to bring it into balance with calcium. This is especially true for our insulin resistant horses.
POTASSIUM
Nutritional Requirement: 0.8%
Purchased Hay: 3.06
Homegrown Hay: 1.4
Excess Potassium – The Silent Killer. Why? Before going any further, please read this article by animal nutritionist Woody Lane – Too Little, Too Much, Early Spring http://veterinarycalendar.dvm360.com/avhc/article/articleDetail.jsp?id=571062&sk=&date=&pageID=3
This article, being devoted to evaluating forage for its risk for producing grass tetany may not seem to be related to horses and their metabolic diseases, but read carefully, about the impact that excessive potassium has on blocking the absorption of calcium and magnesium from the intestinal wall.
In another matter, excessive potassium will fool the body into thinking it has no need for sodium. Sodium intake and thirst are directly linked. Too much potassium intake means too little sodium intake, which means inadequate thirst and water intake. Now contemplate whether your horse simply needs warm water in winter to hydrate itself, or do you need to sprinkle his hay with salt water?
Aside from the Ca:Mg:K ratio predicting metabolic problems, how much K (Potassium) is actually too much? Some writers say that excessive Potassium passes harmlessly through the system and most of it will be urinated out. In light of its impact on Calcium and Magnesium metabolism this obviously is not true. Mr. Lane feels over 3% in the diet is dangerous. I tend to start worrying when the hay goes above 1.5%.
Achieving that low a Potassium level in grass hay is no accident. Mr. Lane partially explains why grass goes so high in K when the plant does not need it. The soil chemistry can be manipulated to suppress “luxury consumption” of K by the grass, but you do have to have a plan.
Grass Tetany Ratio – Ca:Mg:K (Calcium:Magnesium:Potassium)
Tetany Ratio: (potassium% x 256) divided by the sum of (calcium % x 499) plus (magnesium % x 823)
Results greater than 2.2 represent an estimation of increased risk.
Purchased Hay: Potassium - 3.06 x 256 = 783.36
Calcium - .20 x 499 = 99.8
Magnesium - .13 x 823 = 106.99
99.8 + 106.99 = 206.79
783.36 ÷ 206.79 = 3.79
Homegrown Hay: Potassium – 1.40 x 256 = 358.4
Calcium - .50 x 499 = 249.5
Magnesium - .18 x 823 = 148.14
249.5 + 148.14 = 397.64
358.4 ÷ 397.64 = 0.90
Since I am now stuck with seven tons of the purchased hay, I am going to have to devise a serious strategy for managing not only the sugar risk, but almost more importantly, the POTASSIUM risk!
SULPHUR
Nutritional Requirement: .15 (Maximum tolerable 1.25%)
Purchased Hay: .15
Homegrown Hay: .19
Sulphur is needed by plants to help convert nitrogen into protein, notably the essential sulphur-bearing amino acid, methionine. Refer back to Crude Protein, and the Jerry Brunetti article on crude protein to review the equation that helps determine whether your forage contains enough sulphur (10:1 nitrogen to sulphur) to assure that the crude protein is really high quality protein, and not non-protein nitrogen.
THE N:S (NITROGEN:SULPHUR) RATIO
Purchased Hay: 10.30% CP ÷ 6.25 = 1.65 x .1 = .165% Sulphur to help assure quality protein
This hay contains .15% Sulphur
Homegrown Hay: 11.19% CP ÷ 6.25 = 1.79 x .1 = .179% Sulphur to help assure quality protein
This hay contains .19% Sulphur
Even though the purchased hay contains enough Sulphur to theoretically meet the horse’s nutritional requirement, it falls short of being in the correct ratio with nitrogen for proper protein production.
SODIUM
Nutritional Requirement: .10 - .30%
Purchased Hay: .071
Homegrown Hay: .128
See the article Don’t Short Salt by T.W. Swerczek, DVM, Ph.D
http://beefmagazine.com/mag/beef_dont_short_salt/
Even though the homegrown hay is “adequate” for sodium, it could be much better. Why? Because sodium (salt) is protective against excess potassium. The sodium in the homegrown hay is no accident. It was actually applied to the soil as a fertilizer. This practice, when done properly, also has the advantage of offering the grass plants something to take up in spring besides potassium. Although the plant does not need the salt, it will store some salt without damage in compartments called vacuoles. Hay with adequate sodium for animal health is said to be very palatable to the horses.
Rarely will a hay grower add salt to his fertility program, which means that hays grown on sodium deficient ground will almost surely need DELIBERATE supplementation. Because free choice salt is not always interesting to animals (especially those full of excessive potassium), the only way to make sure they are getting enough (roughly 2 oz. per day) is to FEED it to them. My horses quite like slightly salty water sprinkled on their hay. NEVER add salt to drinking water!
CHLORIDE
Nutritional Requirement: .3 - .4%, maximum tolerable level 5%
Purchased Hay: .61
Homegrown Hay: .53
Both hays are slightly above the necessary range, but neither is anywhere near being toxic.
Chloride is the last mineral to be added to the list of known essential minerals, in about 1954. Naturally, chloride comes with salt. Chloride also comes with potassium fertilizer known as Muriate of Potash, which is Potassium Chloride.
Excess chloride will hitch hike along with Potassium in Muriate of Potash (Potassium Chloride) . The grower of the purchased hay could have used Potassium Sulphate instead and brought his sulphur level up a bit. But Potassium Sulphate is more expensive, and that would affect his bottom line. Besides, he doesn’t know that too much chloride is said to be toxic to soil life.
COPPER
Nutritional Requirement: 5-8 ppm (parts per million)
Purchased Hay: 1 ppm
Homegrown Hay: 3 ppm
Copper has proven to be the slipperiest of all the minerals to get into our grass plants. Over the years we have added enough copper to be good for “general cropping “ (Neal Kinsey, Hands On Agronomy). However there are things going on in the soil that perpetually tie it up. My strongest guess is excessive organic matter in our soil (Neal Kinsey, Hands On Agronomy). On other soils in this area, it seems that copper deficiency is a prevalent, but unacknowledged threat to livestock. Our strategy is to attempt to reduce the organic matter to about 8%, to attempt to release the bound-up copper.
MOLYBDENUM
Nutritional Requirement: No requirement established by the National Research Council.
Purchased Hay: 1.7ppm
Homegrown Hay: 3.0ppm
I've marked both in red because of the desperately incorrect ratio of copper to molybdenum in both hays. Both hays are dangerously low in copper. I have found this for EVERY SINGLE HAY ANALYSIS I've read from different parts of the state of Oregon.
I have always had a great fear of molybdenum in excess of a ratio of 10 parts copper to 1 part molybdenum, because of sheep losses due to copper deficiency in the past. Molybdenum is an antagonist of copper.
However, my reading for this article suggests that horses are not nearly as severely affected by moly as ruminants are.
MANGANESE
Nutritional Requirement: 40ppm, Maximum tolerable level, 1000ppm
Purchased Hay: 19ppm
Homegrown Hay: 114ppm
Manganese deficiency can result in defects in lipid and carbohydrate metabolism.
ZINC
Nutritional Requirement: 40ppm, Maximum tolerable level, 500ppm
Purchased Hay: 14ppm
Homegrown Hay: 22ppm
We have not yet added zinc to our fertility program.
BORON
Nutritional Requirement: None Established
Purchased Hay: 1.43ppm
Homegrown Hay: 11.71ppm
Although there is no established daily requirement for boron, virtually all animals on earth are known to require boron. It is active in calcium and hormone metabolism, notably insulin. Therefore, I feel it is very important to know the content of a given hay. Penn State University (I think that’s right!) says that healthy grasses contain around 11ppm boron, on up to 30ppm for legumes. Since there is little to go by, I consider that what is healthy for the plant is healthy for the horse. I consider 11.71ppm boron in the homegrown hay to be adequate, and 1.43ppm in the purchased hay seriously deficient.
Boron is involved in sugar transport within the plant. We are all told that hay cut in the morning will be lower in sugar than hay cut in the afternoon. If you know how to use a Brix refractometer, you can tell yourself. If grass sampled in the morning has the same Brix reading (for sugar) as grass sampled in the afternoon, there is a strong possibility that the grass is boron deficient and that the sugar transport from the leaf to other parts of the plant (roots) is inoperable.
DIGESTIBLE ENERGY
Nutritional Requirement: Varies. The DE Mcal/lb. value will be used to judge how much hay the horse gets in its ration each day.
Purchased Hay: .90 Mcal/lb.
Homegrown Hay: 1.03 Mcal/lb.
The higher digestible energy is probably due to the higher sugar in the homegrown hay.
LIGNIN
Lignin is the indigestible fiber in the plant. Excessive lignin will reduce availability of nutrients, making the hay less digestible.
Purchased Hay: 5.72%
Homegrown Hay: 3.11%
The homegrown hay appears to be somewhat more digestible.
RELATIVE FEED VALUE
Relative Feed Value (RFV) is an index that combines digestibility estimates of Acid Detergent Fiber and intake estimates of Non Detergent Fiber. The reference value of 100 is based on full-bloom alfalfa. Theoretically, hay with 110 RFV would have 10% more energy than full bloom alfalfa.
http://www.wa-hay.org/business/newsletters/march02.pdf
Purchased Hay: 95
Homegrown Hay: 105
TOTAL DIGESTIBLE NUTRIENTS
An estimate of the digestibility of the forage.
Purchased Hay: 45.12
Homegrown Hay: 51.64
CONCLUSION:
There are still many things that I have to learn about extracting useful information out of a forage analysis. There are still numerous ratios between the major and minor minerals to memorize and apply. I do not know them all.
While neither of the hays is perfect, it appears that the only real saving grace of the purchased hay is that I may be able to feed more of it, especially in light of the fact that I am going to have to soak it to remove excess potassium. (Update: Rather than soak the purchased hay, we are combining it with the much lower potassium homegrown.)
It looks as though we don’t get “something for nothing” after all, in terms of outlay of effort.
Our cost for fertility elements and contracted haying services are pretty much equal, whether we buy or bale. When we grow our own we are also tasked with picking the hay up out of the field and stacking it in the barn. We are out in the rain during fall and spring, liming and fertilizing. We are running back and forth to the fertilizer dealer some 25 miles away.
But the cost of the commercially grown hay only begins with the $255 per ton. I am going to have to soak this stuff, and try to figure out how to balance nutrients. I have to face the knowledge that because the hay is deficient in so many areas, complete nutrition in the form of vitamins, enzymes, immune substances, pigments, and a whole host of phytonutrients are lost, because the growing orchard grass was not provided with the necessary minerals to catalyze them into existence.
The main worry I have is the potential aggravation of the horses’ metabolic problems. My older horse has recently been guardedly diagnosed with potential cancer (we are not going looking for it.) His resistance will be down.
I couldn’t save our hay crop this year. It was pounded to the ground by late rains until it began to rot. That was a blow, and made me turn away from my involvement with producing our own hay. The life of a farmer is too uncertain.
But the life of letting someone else take care of things for me is far more uncertain. This coming year, I will have a different strategy, and a healthier respect for what we have managed to achieve in our effort to manipulate soil chemistry to produce the healthiest possible hay.
UPDATE: Since I originally wrote this, I have gained a new understanding of potassium’s role in horses at heavy exercise. Please see the post, “Sweat and “Excess” Potassium. I will be elaborating on this aspect of potassium and perhaps the impact of exercise in moderating its effect on calcium and magnesium metabolism.